1863 ning garai n du shi yang, masha ni chye ai hte jai lang ai silicon- n-gun yawng gaw, shingra tara silicon-dai hta lawm ai arung arai ni hpe, ceramic, cement, hte glass zawn re ai, dai ni na aten na arung arai ni de galai shai kau ai, inorganic silicon a n-gun rawng ai n-gun ni rai nga ai. 1863 ning hta, French tsi hpaji ninghkring ni C. Feidedel hte JM raft ni hpe shingdaw ai tetraethyl silane ni gaw, ethyl zinc a n-gun atsam hte silicon tetrafluoride hpe shinggrup da ai hka htung langai mi hta n-gun rawng ai hku bai htang ai majaw re. Labau hta shawng nnan na organosilicon compound rai nga ai. Ndai lam gaw organo ga chemistry a npawt nhpang hpe mung masat da ya ai.
Dai aten kaw nna, chemist ni gaw, hkum hkrang daw ni hpe matut manoi galaw ai. Dai ni hta, A. Lamenberg, ethyl ortho galite hpe lang nna, silicon tetrachloride hpe galai na matu, alkyl zinc hte bai htang na matu, organosilicon compounds ni hpe mono-, II-, hte III silicon magam bungli ni, A.Polis ni hpe tsun dan na matu manu dan ai. tetraphenylsilane, CAWurtz a n-gun atsam hku nna. 1903 ning du hkra 40 ning du hkra, silicone hpe teng sha rawt jat galu kaba wa hkra n-gun jaw ya ai hpaji masa hta awng dang ai lam n nga ai raitim, ndai aten laman hta, chemist ni gaw, ningshawng bungli law law galaw ma ai. Dai majaw, ndai madang hpe silicone hpe hpaw ninghtan ai aten ngu nna sawn la mai ai.
Mying kaba ai British chemist FSKipping hpe organosilicon chemistry hpe hpaw ninghtan ai wa ngu masat da ai. 1898 ning kaw nna 1944 ning du hkra, ndai lam hta sung sung sawk sagawn ai lam ni hpe galaw nna, dai hte seng ai laika buk 51 hpe matut manoi shapraw ai.
1904 ning hta, W hte Germany mungdan na chemist Dithey yan gaw, Grignard a n-gun atsam hku nna, organosilicon compounds ni hpe shingdaw lu ai hpe, shi hkrai shi mu tam wa ma ai. Ndai ladat gaw, bungli galaw ai lam loi ai, hkai lu hkai sha ai lam law ai, jai lang ai lam law ai hte shim lum ai lam grai law ai majaw, shawng na magri{2}}}organic synthesis ladat ni hta grau nna rawt jat wa ai. Ndai ladat hpe lang nna, n bung ai silicon bungli galaw ai lam ni hte hkum hkrang daw ni hpe shingdaw nna galaw mai ai.
Kip-ping gaw ndai ladat hpe jai lang nna, hka htung-} lachyum shaleng da ai n-gun law law hpe shingdaw yu ai. Ndai ladat gaw htawm hpang de organoicicon hpaga lam a npawt nhpang tai wa sai rai nna, dai ni aten hta organosiliccon a matu ahkyak dik htum ai synthesis ladat langai mi hku nna naw nga nga ai. RMgCl+SiCl{5} RSiCl:+RSiCl+R:SiCiChiCl +MgCl,(2.3) Grignard reagent ladat hpe jai lang nna, shingdaw ai organochlorosiles ni hpe lang nna, shanhte hpe silanol ni hpe hka ja mai ai hpe mu lu ai. Dai aten hta sha, silaneniol hte siltriol gaw, polymers ni hpe hpaw na matu, lapran na condensation hpe grau nna hkam sha lu ai hpe mung sadi hkrup ai. Raitim, organic chemist langai hku nna, shi gaw ndai bai htang ai lam hpe tsep kawp n myit yu ai sha, ndai polymer arung arai ni hpe pyi n dawng n yawt ai. Dai majaw, dai hpe n hkaja wa ai. Ndai lam hte seng nna, Dilthey gaw lachyum rawng ai bungli galaw ai: shi gaw, hexaphenylrixane hpe lu la na matu, diphenylsiladiol hpe hkap la ai. Ndai gaw labau hta shawng ningnan lang cyclic polysiloxane compound rai nga ai. Dai gaw linear silicon-one hpe shingdaw ai lam hta ningshawng langai rai nna, shi a du sa ai lam gaw organosilicon polymers ni hpe gyin shalat ai hta grai kaja ai lit hpe gun hpai wa sai.
1904 ning kaw nna 1937 ning du hkra, hpaji ninghkring ni gaw, asan sha nga ai organosilicon compound law law hpe shapraw ai sha n-ga, cyclic hte linear polysixysaccharides ni hpe mung galaw shapraw ma ai. Dai hta n-ga, A.Stock gaw, npawt nhpang sawk sagawn ai lam hta silahydhy law law hpe mu tam wa sai rai nna, asymmetric silicon atom compounds ni hpe shingdaw ai lam hpe galaw hpang wa sai. Lai wa sai shaning sumshi ning gaw, hkum hkrang daw ni hpe n-gun jaw ai lam a matu rawt jat galu kaba wa ai aten rai nga ai.
1930 ning na ai hpang Chemists ni gaw, n-gun kaba ai{1}}}molecular organoicular compounds ni a matu jai lang na myit mada lam hpe chye na hpang wa ma ai. Ndai lam hta shawng nnan na sawk sagawn ai ni hta, Amerikan mungdan na JFHy of Corning Glass Company, WJ Petnode hte Electric (GE) a EGRochow, America mungdan na General Electric (GE), hte Germany kaw na R. Miller, ngu ai, moi na Soviet Munghpawm Mungdan Andrianov hte BNDolgov ni a KA, etc.
Hyde gaw, Kipping a ningmu hte nhtan shai ai hku nna, organosilicon chemistry hpe polymer chemistry hte shawng nnan lang hpawng de ai wa re. Shi a lam matsun ai npu hta, Corning Inc. gaw silicone resin, coatings, n-gun n rawng ai tsi ni hte kaga polyoronoxane arung arai law law hpe wan n-gun n-gun n-rawng ai glass hpun palawng ni hpe shapraw ya ai. Dai aten hta, DowChemicals na DowChemicals gaw 1942 ning hta dimethyl silicone sau hte methyl silicone resin a matu n-gun ja ai hpun ni hpe sawk sagawn ai lam hpe mung galaw hpang wa ai. dai aten. 1940 ning hta, Rochow gaw methylilane a "direct synthesis ladat" hpe hpan shalat nna, patent hpe hpyi shawn ai. Ndai ladat gaw hparan ladat n lang ai. Dai gaw, chloromethane hpe magri n-gun rawng ai silicon powder de hkrak bang da ai gas{8}}solid phase reaction rai nga ai (Equation 2.4). Ndai aten hta sha, German chemist Muller mung dai hte bung ai patent hpe hpyi shawn ai raitim, ahkyak ai aten gaw Rochow a shata 9 hpang hkrat ai. Ndai laklai ai garum shingtau lam gaw silicone hpe galaw shapraw ai hta rawt malan lam kaba hpe shabyin ya nna, silicone hpaga lam hpe matut nna rawt jat galu kaba wa hkra n-gun jaw ya nga ai.
1943 ning hta, Dow Chemical Company hte Corning Inc. ni gaw mungkan-ren ai silicone hpaji ninghkring company hpe jawm gawgap nna, dai shaning hta sha, polyraronoxanes galaw shapraw ai jak rung langai hpe, Mdan, Michigan, USA kaw galaw shapraw na matu, jak rung langai mi hpe gawgap da ai. Company gaw kade nna yang DC#4 ignition hpe pat da ai arung arai ni hpe gyin shalat nna, tsaw ai{6}}}}}} ]altitude hpe awng dang hkra jai lang wa sai. Hpang e, dai company gaw silicone resin amyu myu, n-gun n rawng ai sau, sau sau, wan n-gun shayawm ai ni hte kaga arung arai ni hpe galaw shapraw ai. 1947 ning hta, General Electric Company gaw, shinggyim hkum hkrang hta n-gun n-gun (organosilicon) hpe mung hpaw nna, dai gaw, hkrak ai ladat hku nna, hkum hkrang n-gun hpe shapraw nna, polysiloxane arung arai ni hpe shapraw ya ai. General Electric Company hpe galaw shapraw ai hpaji hpe hpang na silicone jak rung ni hkap la ai.
Moi na Soviet Union hta silicone polymers ni a lam hpe sawk sagawn ai lam gaw grai laklai ai lam rai nga ai, grau nna Andrianov. Polysiloxane polymers ni hta bungli law law galaw ai hta n-ga, organosilic polymer law law hpe tatut jai lang ai manu hte shingdaw nna galaw ai hta n-ga, kaga lam ni rai nga ai boron, aluminum, tin, tin hte phosphorus zawn re ai kaga lam ni hpe mung, polysiloxane structure de galai shai na matu mung bang da ai. Shi gaw hka n shang hkra galaw ai sumla hku nna silazane hpe shawng nnan lang ai wa mung rai nga ai.
Mungkan majan II ngut ai hpang, hpyen masa galaw shapraw ai hta silicone arung arai ni hpe awng dang ai hku jai lang ai majaw, silicone hpaga lam gaw grai lawan ai hku rawt jat wa nna, dai hpe galaw shapraw ai lam yawng gaw, aten dep lam langai mi de du wa sai. 1950 ning daram hta, silicone arung arai galaw shapraw ai company ni hpe mungdan shagu hta hkan nna, matut manoi hpaw hpang wa sai. Silicone polymer arung arai amyu myu, silicone rubber (Bambber tsaw ai, nta kata na nbung katsi ai hpe n-gun jaw ai, n-gun n rawng ai silicone rubber, sau{4} hpe ninghkap lu ai fluorosililicone rubber, etc.)), diffusion pump sau, laminting resin, silicone surfactant, silicone surfactant, anti{6}}stickking agent, silicone zawn re ai arung arai amyu myu. rubber ablation arung arai, etc., ni gaw langai hpang langai pru wa sai.
1938 hte 1965 lapran, theory hte jai lang ai lam lahkawng yan hta; Organosilicon chemistry gaw monomers hte polymers ni hta lawan ai hku rawt jat wa nga ai. Ndai shara hta, ahkyak ai lam ni hpe ahkyak shatai nna tsun dan ai lam ni gaw: silicylation reactions, hydrosilylation reactions, photoactive organosilicon compounds ni a ntsa sawk sagawn ai lam, carbon functional group ni lawm ai organosilicon compounds ni hpe hpaw shabawn ai lam, n-gun jat wa ai ladat ni hpe sawk sagawn ai lam, polymerization ladat ni hpe grau kaja hkra galaw ai lam, silicone sau, silicone rubber, hte coupling agents ni a hpang jahtum byin pru wa ai lam ni lawm ai.
1965 ning kaw nna, ya nga ai awng dang lam ni hpe ngang grin hkra, rawt jat galu kaba wa hkra, gram lajang ai hte jai lang ai lam ni hta n-ga, masha ni gaw organolicon chemistry hpaji ningnan de mung kayin wa sai. Dai ni hta, dan dawng ai ni hta lawm ai: hkum hkrang shamu shamawt ai lam, cyclic hte linear polysilanes ni lawm ai organosilicon stereochemistry, organosilicon compounds ni, silicon{2}} amyu myu hku nna, silicon, silicon{3}}metal bond ni lawm ai silicon n-gun n-gun ni, n-gun n rawng ai n-gun n-gun ni, n-gun n-gun n-gun ni, n-gun n-gun ni hpe n-gun jaw ai lam ni lawm ai. copolymers, sesquiloxan, silicon- hta lawm ai dendritic hte hyperbranched polymer compounds ni, etc. Silicone hpaga lam hta, silicone monomers hte polymers ni a galaw shapraw ai shadawn shadang gaw, ayan jat wa nga ai, galaw shapraw ai hpaji masa ni gaw, n-gun n yawm ai sha, galaw shapraw ai manu ni gaw, n-gun yawm wa nga ai. Ndai lam gaw silicone arung arai ni hpe grau shingjawng lu shangun ai. Multi{8}} bungli matut manoi galaw ai lam hte tsaw ai{9}}performance silicone arung arai ni, ga shadawn, tsi hpaji, n-gun rawng ai hte n-gun rawng ai polysiloxes ni gaw, shanhte a application scope hpe matut manoi jat wa shangun ai. Silicone arung arai ni gaw, silicone sau, silicone rubber, silicone resin, silane coupling agents zawn re ai madung hkrang ni hta, mungdan sut masa lam amyu myu de ayan shang wa nga ai.